SECTION-4 (Maximum Marks : 12)
• This section contains FOUR (04) Matching List Sets.
• Each set has ONE Multiple Choice Question.
• Each set has TWO lists: List-I and List-II.
• List-I has Four entries (P), (Q), (R) and (S) and List-II has Five entries (1), (2), (3), (4) and (5).
• FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the condition asked in the Multiple Choice Question.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks
ONLY if the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : -1 In all other cases.
In a conductometric titration, small volume of titrant of higher concentration is added stepwise to a larger volume of titrate of much lower concentration, and the conductance is measured after each addition. The limiting ionic conductivity ( ) values (in
) for different ions in aqueous solutions are given below:
Ions | |||||||||
6.2 | 7.4 | 5.0 | 35.0 | 7.2 | 7.6 | 16.0 | 19.9 | 4.1 |
For different combinations of titrates and titrants given in List-I, the graphs of 'conductance' versus 'volume of titrant' are given in List-II. Match each entry in List-I with the appropriate entry in List-II and choose the correct option.
List-I | List-II | ||
Titrate: Titrant: | (1) | ||
Titrate: Titrant: | (2) | ||
Titrate: Titrant: | (3) | ||
Titrate: Titrant: | (4) | ||
(5) |
Text Solution
Verified by ExpertsC
Sol. (P) 
is replaced by 
Conductance will first decrease and then after equivalence point, it will increase

(Q)
is replaced by 
Conductance will first increase slightly and then will increase further
(R) 
is replaced by 
(S)
is replaced by
conductance will first decrease and them become almost constant due to buffer formation.
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